PBI (Polybenzimidazole) Machining: Data & Grades | Beaulic

PBI — polybenzimidazole

No thermoplastic carries more load at higher temperature. PBI keeps 380 MPa of compressive strength at 400 °C, expands less than PEEK, and will not burn in air. It is also the most difficult grade we machine — brittle, moisture-hungry and available only in a narrow range of stock sizes.

400 °C in inert 380 MPa compressive LOI 58 % — self-extinguishing Rod & plate only a.k.a. Celazole
435°C
Heat deflection temperature (0.45 MPa)
380MPa
Compressive strength at 23 °C
23µm/m·K
Coefficient of thermal expansion
1.30g/cm³
Density
Property data

Typical values, unfilled PBI

Values for a Celazole U-60 class moulded stock shape. Glass-filled and graphite-modified versions exist for wear duty, with proportionally lower strength.

PropertyValueWhat it means in design
Heat deflection temperature435 °C at 0.45 MPaThe highest of any machinable thermoplastic — the reason PBI exists
Continuous service temperature~400 °C inert, ~300 °C in airOxidation limits air service; purge or inert-gas environments unlock the full range
Compressive strength~380 MPaRoughly double PEEK — carries valve-seat and seal loads metal-free
Tensile strength~160 MPaHigh, but elongation is only 3 % — very little plastic deformation before failure
Flexural modulus~5.9 GPaThe stiffest grade in our range; deflection is rarely the design limit
Coefficient of thermal expansion~23 µm/m·KClose to stainless steel, which simplifies metal-to-polymer fits
Water absorption~0.4 % / 24 h, higher at saturationParts grow measurably in humid air — condition before finishing and before final inspection
Limiting oxygen index58 %Will not sustain combustion in air; negligible smoke
Chemical resistanceGood, with clear exceptionsResists fuels, oils, glycols and alcohols; attacked by strong alkalis and hot concentrated acids
MachinabilityDifficultAbrasive and notch-sensitive; expect slower cycles and higher inspection cost
AvailabilityRod, plate, limited sizesLarge or thick sections may not exist as stock — check before you design around them
Cost index30–50 × PMMAThe most expensive grade we quote; specify it only where the duty demands it
Forms & grades

What is actually obtainable

Unfilled rod & plate

Standard U-60 class material, machined from moulded stock. The default for insulators, seal rings and high-temperature fixtures.

Glass-filled

Improved dimensional stability and wear resistance with reduced strength. Abrasive to tooling; we plan extra tool changes into the cycle.

Graphite-modified

Lower friction and thermal expansion for bearing and seal duty, at the price of electrical insulation — graphite grades are conductive.

Stock size limits

Rod up to roughly 75 mm and plate to about 25 mm thickness are standard. Beyond that, lead time and cost rise steeply — tell us early if the design needs more.

Near-net blanks

For large parts we quote a moulded near-net blank plus finish machining, which is usually cheaper than machining everything out of plate.

Certification

Lot certificate, dimensional report and material traceability as standard. First-article inspection to AS9102 available on request.

Process notes

Machining PBI: slow, sharp and dry

  • Condition the blank first. PBI picks up moisture and grows. We bring stock to 23 °C / 50 % RH equilibrium before the finishing operation, and measure under the same conditions.
  • Sharp carbide, small depths. 0.2–0.5 mm radial stepovers, high spindle speed, low feed. PBI is abrasive and work-hardens the cutting edge quickly — we change tools on a count, not on noise.
  • Dry or air blast. No water-based coolant on finishing cuts. Chips are fine and hot; extraction is mandatory, not optional.
  • Stress relief. A staged ramp to 200 °C after roughing, cooled under restraint, removes the moulded-in stress that warps thin walls.
  • Assume brittle. No sharp internal corners, no thin unsupported ribs, no press fits without a calculated interference. Radius everything and specify chamfers.
  • Clamping. Soft jaws machined to the contour, minimum clamping force, support directly under the cut. Point-loading a PBI plate will crack it.
  • Threads and inserts. Coarse threads chip at the crest; use fine threads or bonded inserts for anything that will be assembled more than once.
  • Tolerance. ±0.05 mm is the practical default. Tighter is possible on small, stable features with conditioned stock and temperature-controlled inspection.
Applications

Where PBI replaces metal and ceramic

Oil & gas

Seal rings, valve seats, backup rings and wear components for downhole tools at 250 °C+ in brine and hydrocarbon service.

Semiconductor

High-temperature wafer handling, chamber fixtures and insulators that must not outgas or shed particles at process temperature.

Aerospace

Bushings, seals and thermal isolators close to engines, where the fire-performance requirement rules out other polymers.

Glass & hot forming

Contact pads, guides and fixtures for hot glass handling — PBI does not scratch the ware and survives the radiant heat.

Furnace & lab fixtures

Insulating spacers, supports and sample holders for furnaces and autoclaves where ceramic would crack on thermal shock.

High-load insulation

Electrical isolation under mechanical load at temperature — the combination that eliminates both metal and ceramic.

Compare

PBI alternatives

PBI is the last resort before ceramic. Confirm you actually need 400 °C before accepting the cost and lead time.

Designing beyond 300 °C?

Send the duty cycle, media and load. We will tell you honestly whether PBI is needed, or whether PI or PEEK will do the job at a fraction of the cost.

Talk to an engineer